|
Following
are the main points of electron pair repulsion theory:
There are two types of electron pairs surrounding the central atom.
Bond
pair.
Lone
pair.
These bond pairs are known as active set of electrons.
These electron pairs (bond pairs or lone pairs) repel each other.
Due to repulsion, electron pairs of central atom try to be as far as possible.
Hence, they arrange themselves in space in such a manner that the force
of repulsion between them is minimized.
The force of repulsion between lone pairs and bond pairs is not the same.
The order of repulsion is as follows:
lone
pair-lone pair>lone pair-bond pair>bond pair-bond pair.
Pi-electron pairs are not considered as an active set of electrons.
The shape of molecule depends upon total number of electron pairs surrounding
the central atom.
For
example:
If
central atom has two electron pairs, geometry of molecule will be linear
with bond angles of 180o.
If
central atom has three electron pairs, geometry of molecule will be trigonal
with bond angles of 120o.
If
central atom has four electron pairs, geometry of molecule will be tetrahedral
with bond angles of 109.5o
|