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Three
States of Matter
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Gas
laws
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Boyle’s
law
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| Introduction
Boyle’s law is a quantitative relationship between volume and pressure of a gas at constant temperature. Statement "The volume of a given mass of a gas is inversely proportional to pressure if temperature remains constant ". Mathematical representation of Boyle’s law |
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According
to Boyle’s law
V µ 1/P V=
(constant)(1/P)
PV=constant At P1 pressure P1V1 = constant ------------------(1) At P2 pressure P2V2 = constant ------------------(2) Comparing (1) & ( 2) P1V1 = P2V2 . |
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| Second
statement "At constant temperature, the product of pressure and volume of a gas remains constant " |
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| Graphical
representation of Boyle’s law Graph between P & V at constant temperature is a smooth curve known as "parabola" |
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| Graph between 1/P & V at constant temperature is a straight line. | ||
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Charles
law
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Introduction |
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| It is quantitative relation between volume and absolute temperature of a gas at constant pressure. | ||
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Statement |
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| "The volume of a given mass of a gas at constant pressure is directly proportional to absolute temperature" | ||
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Second statement |
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"The volume of a given mass of a gas increases or decreases by 1/273 times of it’s original volume at 0 0C for every degree fall or rise of temperature at given pressure." |
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For
latest information , free computer courses and high impact notes visit
: www.citycollegiate.com
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Mathematical representation |
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Let
the volume of a gas at T Kelvin is V V/T = constant
At T1 k Thus |
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Third statement |
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using above equation ,Charles’s law can also be stated as:
"The ratio of volume to absolute temperature of a gas at given pressure is always constant" Graphical representationGraph between Volume and absolute temperature of a gas at constant pressure is a "straight line" |
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| Absolute scale of temperature or absolute zero | ||
| If the graph between V and T is extra plotted, it intersects T-axis at -273.16 0C At -273.16 0C volume of any gas theoretically becomes zero as indicated by the graph. | ||
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| But practically volume of a gas can never become zero. Actually no gas can achieve the lowest possible temperature and before -273.16 0C all gases are condensed to liquid. This temperature is referred to as absolute scale or absolute zero. At -273.16 0C all molecular motions are ceased. | ||